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Beilstein J. Org. Chem. 2018, 14, 1758–1768, doi:10.3762/bjoc.14.150
Graphical Abstract
Figure 1: Targeted multivalent phototherapeutic agent and its calix[4]arene-based precursor. RGD = Arg–Gly–As...
Scheme 1: Synthesis of RuII-calix[4]arene complex 7.
Scheme 2: Synthesis of RuII-calix[4]arene-[c-(RGDfK)]4 conjugate 9.
Figure 2: MD snapshot showing an optimized model of conjugate 9. RGDfK units are depicted in orange ribbons, ...
Figure 3: Absorption and emission spectra of RuII-calix[4]arene-[c-(RGDfK)]4 conjugate 9 in water.
Figure 4: Luminescence intensity and excited state lifetime of conjugate 9 in the presence of GMP measured in...
Figure 5: Transient absorption spectra of RuII-calix[4]arene-[c-(RGDfK)]4 conjugate 9 (in 10 mM Tris·HCl buff...
Figure 6: MALDI–MS analysis of a solution containing conjugate 9 and GMP after continuous light irradiation. ...